Product ID:G-G ALKYD ENAMEL BLACK, 14551
MSDS Date:04/17/1990
FSC:8010
NIIN:00N020650
MSDS Number: BLKLH

GLIDDEN COMPANY

925 EUCLID AVENUE
CLEVELAND, OH 44115
US

Emergency Phone: 216-826-5566

Info Phone: 216-826-5566

Cage: 01PD6

GLIDDEN PAINT, ICI PAINTS NORTH AMERICA

CLEVELAND, OH 44115 US

Telephone: 800-545-2643/216-344-8207

Cage: 01PD6

TREATED CLAY; (QUATERNARY AMMONIUM COMPOUNDS,

CAS: 71011-27-3

Fraction By Weight: 1-5%

ACGIH TLV: 10 MG/M3 (MFR)

HYDROTREATED LIGHT (PETROLEUM) DISTILLATE.

CAS: 64742-47-8

Fraction By Weight: 5-10%

OSHA PEL 100 PPM (MFR)

ACGIH TLV: 100 PPM (MFR)

FATTY ACIDS,TALL-OIL,POLYMERS W/GLYCEROL,ISOPHTHALIC

CAS: 68459-17-6

Fraction By Weight: 20-30%

FATTY ACIDS, TALL-OIL, POLYMERS WITH GLYCEROL,

CAS: 66070-62-0

Fraction By Weight: 10-20%

SOLVENT NAPHTHA (PETROLEUM) MEDIUM ALIPHATIC; (MINERAL

CAS: 64742-88-7

Fraction By Weight: 40-50%

OSHA PEL 100 PPM (MFR)

ACGIH TLV: 100 PPM (MFR)

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

Fraction By Weight: 1-5%

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3; 9192

LD50 LC50 Mixture:SEE INGREDIENT #4.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL:IRRIT OF RESP TRACT, PRLNG INHAL
MAY LEAD TO FATG/DROW/DIZZ &/OR LT HEAD/HDCH/UNCOORD/NAUS/CNS
DEPRESS/DFCLTY BRTHG/UNCON/ASPHY/DEATH. SKIN: IRRIT. PRLNG/RPTD
CNTCT CAN CAUSE DERM/DEFAT/ BLURRED VISION. EYE:IRRIT. PRLNG/RPTD
CNTCT CAN CAUSE BLURRED VISION/TEARING/REDNESS/SEV IRRIT. INGEST:
MAY (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:CAUSE FATG/DROW/DIZZ &/OR LT HEAD/
UNCOORD/NAUS/VOMIT/DIARRHEA/DIGESTIVE SYS PROBS/CNS DEPRESS. RPTS
HAVE ASSOC RPTD/PRLNG OCCUP OVEREXP TO SOLVS W/PERMANENT BRAIN &
NERV SYS DMG. INTENT MISU SE BY DELIB CONC/INHAL CONTENTS MAY BE
HARMFUL/FATAL. AMTS INGESTED INCIDENTAL TO CONSUMER/INDUS HNDLG ARE
NOT(SUPDAT)
Medical Cond Aggravated by Exposure:EYE, SKIN, RESPIRATORY DISORDERS,
LUNG DISORDERS, ASTHMA-LIKE CONDITIONS.

First Aid:INHAL:REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED BRTHG.
GET EMER MED ATTN. HAVE TRAINED PERS GIVE O*2 IF NEC. GET MD FOR
ANY BRTHG DFCLTY. SKIN:WASH OFF QUICKLY W/PLENTY OF H*20, THEN SOAP
& H*2 0. REMOVE CONTAM CLTHG & WASH BEFORE REUSE. EYE:FLUSH IMMED
W/LG AMTS OF H*20, ESP UNDER LIDS FOR @ LST 15 MIN. GET EMER MED
ATTEN. INGEST:GET MD IMMEDIATELY.

Flash Point Method:SCC
Flash Point:102F,39C
Lower Limits:1%
Extinguishing Media:DRY CHEMICAL OR FOAM.
Fire Fighting Procedures:WATER MAY BE USED TO COOL & PROTECT EXPOSED
CNTNRS. WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:CLSD CNTNRS MAY EXPLODE WHEN EXPOSED TO
EXTREME HEAT/FIRE. VAPS CAN FORM EXPLO MIXT IN AIR @ ELEVATED
TEMPS. MAY DECOMPOSE UNDER FIRE CNDTNS EMITTING (SUPDAT)

Spill Release Procedures:COMPLY W/ALL APPLIC HLTH & ENVIRON REGS. ELIM
ALL SOURCES OF IGNIT. VENT AREA. SPILLS MAY BE COLLECTED W/ABSORB
MATLS. LG SPILLS:SHUT OFF LEAK IF SAFE TO DO SO. DIKE & CONTAIN
SPILL. PUMP TO STOR/SALV AGE VESSELS. USE ABSORB TO PICK UP EXCESS
(SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE BELOW 100F. KEEP AWAY FROM
HEAT/SPKS/OPEN FLAME. USE ONLY W/ADEQ VENT. DO NOT TAKE INTERNALLY.
KEEP OUT OF REACH OF CHILDREN.
Other Precautions:AVOID CNTCT W/SKIN/EYES & BRTHG OF VAPS. KEEP CNTNRS
TIGHTLY CLSD & UPRIGHT WHEN NOT IN USE. EMPTY CNTNRS MAY CONTAIN
HAZ RESIDUES. GROUND EQUIP WHEN TRANSFERRING TO PREVENT
ACCUMULATION OF STATIC CHA RGE.

Respiratory Protection:CONTROL ENVIRON CONC BELOW APPLIC STDS. WHERE
RESP PROT IS REQD, USE ONLY NIOSH/MSHA APPRVD RESPIRATORS I/A/W
OSHA STD 29 CFR 1910.134. IF SANDING IS DONE, WEAR NIOSH/MSHA
APPROVED DUST MASK TO AVOID BRTHG OF SANDING DUST.
Ventilation:PROVIDE DILUTION OF VENTILATION OR LOCAL EXHAUST TO PREVENT
BUILD-UP OF VAPORS.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH & SAFETY SHOWER.
Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER HANDLING,
ESPECIALLY BEFORE EATING OR SMOKING.
Supplemental Safety and Health
EXPLO HAZ:IRRIT &/OR TOXIC GASES. EFTS OF OVEREXP:LIKELY TO CAUSE
INJURY; HOWEVER, INGEST OF LARGER AMTS MAY CAUSE LUNG INFLAMMATION
& DAMAGE DUE TO ASPIRATION OF MATERIAL INTO LUNGS. SPILL PROC:RESID
UE. KEEP SALVAGE MATL & RINSE WATER OUTOF SEWERS/WATERCOURSES.

HCC:F4
Spec Gravity:0.912
Appearance and Odor:BLACK LIQUID.
Percent Volatiles by Volume:60.30

Stability Indicator/Materials to Avoid:YES
OXIDIZERS, ACIDS, BASES, AMINES.
Stability Condition to Avoid:ELEVATED TEMPERATURES, CONTACT WITH
OXIDIZING AGENT.
Hazardous Decomposition Products:CO & CO*2.

Waste Disposal Methods:DISPOSE I/A/W ALL APPLICABLE FEDERAL, STATE &
LOCAL REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.